Tuesday, March 14, 2023
Room-Temperature Superconductor Discovery Meets With Resistance
Every single discovery of a long sought research target recieves the same nonsense from even informed folk because thhey simply cannot know yet. These are experts and have been also bit. I do not see them getting it wrong.
Now turning all this into useful tools will come along quickly, simply because we are in the temperature sweet spot and can eschew a massive infrastructure build.
This is also good news.
Room-Temperature Superconductor Discovery Meets With Resistance
A paper in Nature reports the discovery of a superconductor that operates at room temperatures and near-room pressures. The claim has divided the research community.
One hallmark of superconductivity is the Meissner effect, which expels all magnetic fields from a material — a property that allows a superconductor to levitate, as seen here. The researchers claim to observe the Meissner effect in their new material.
March 8, 2023
In a packed talk on Tuesday afternoon at the American Physical Society’s annual March meeting in Las Vegas, Ranga Dias, a physicist at the University of Rochester, announced that he and his team had achieved a century-old dream of the field: a superconductor that works at room temperature and near-room pressure. Interest was so intense in the presentation that security personnel stopped entry to the overflowing room more than fifteen minutes before the talk. They could be overheard shooing curious onlookers away shortly before Dias began speaking.
The results, published today in Nature, appear to show that a conventional conductor — a solid composed of hydrogen, nitrogen and the rare-earth metal lutetium — was transformed into a flawless material capable of conducting electricity with perfect efficiency.
While the announcement has been greeted with enthusiasm by some scientists, others are far more cautious, pointing to the research group’s controversial history of alleged research malfeasance. (Dias strongly denies the accusations.) Reactions by 10 independent experts contacted by Quanta ranged from unbridled excitement to outright dismissal, with many of the experts expressing some version of cautious optimism.
Previously, superconductivity has been observed only at frigid temperatures or crushing pressures — conditions that make those materials impractical for long-desired applications such as lossless power lines, levitating high-speed trains and affordable medical imaging devices. The newly forged compound conducts current with no resistance at 21 degrees Celsius (69.8 degrees Fahrenheit) and at a pressure of around 1 gigapascal. That’s still a lot of pressure — roughly 10 times the pressure at the deepest point in the Marianas Trench — but it’s more than 100 times less intense than the pressure required in previous experiments with similar materials.
“If it turns out to be correct, it’s possibly the biggest breakthrough in the history of superconductivity,” said James Hamlin, a physicist at the University of Florida who was not involved in the work. If it’s true, he said, “it’s an earth-shattering, groundbreaking, very exciting discovery.” But incidents involving the team’s previous work — including but not limited to a near-room-temperature superconductivity claim published in Nature in 2020 and retracted late last year — have cast a shadow across today’s announcement. “It’s hard to not wonder if some of the same problems that have gone unaddressed in previous work also exist in the new work,” Hamlin said.
Hitting All the Benchmarks
For more than a century, scientists have known that cooling most metals to temperatures within a few degrees of absolute zero brings about a dramatic metamorphosis. Around this “critical temperature,” which varies from one material to another, electrons pair up and form a type of quantum fluid. Once this happens, electrons no longer bounce into atoms in the material — interactions that generate resistance — which allows them to flow with no energy loss.
The overarching goal of superconductivity research since then has been to raise the critical temperature.
For decades, physicists have made incremental progress, steadily raising the critical temperature by testing different combinations of elements. One promising class of materials, known as hydrides, emerged in recent years. Hydrides are compounds that combine the featherweight hydrogen with heavier atoms like sulfur or metals. The more hydrogen, the better for superconductivity, physicists believe. Researchers sometimes add in a dusting of other atoms, such as carbon or nitrogen, to further tweak its properties. The first superconducting hydride, reported in 2015, hit its transition at around minus 70 degrees Celsius and 155 gigapascals of pressure (approaching half that of Earth’s core). Within three years, the same group and another both whipped up even more hydrogen-rich “superhydride” materials that could superconduct as high as minus 13 degrees Celsius and at 190 gigapascals.
The rare-earth metal lutetium was transformed into a room-temperature superconductor in the new research.
The new study demolishes all past records. For the past few years, Dias’ team has worked on a superhydride based on lutetium. To produce a sample, the team would bathe a thin film of lutetium in a perfume of 99% hydrogen and 1% nitrogen while baking it for a few days at 200 degrees Celsius. A diamond anvil cell would then compress the sample at 2 gigapascals of pressure. The team would then progressively loosen the anvil while testing the sample for superconducting properties. Dias said that out of hundreds of samples produced, they were able to observe superconductivity in dozens of samples even after the pressure was lowered to about 1 gigapascal.
To demonstrate superconductivity, the team hit three textbook benchmarks. At the critical temperature, they showed a drop in resistance and a peak in a property related to how readily a material warms up. The team also managed to directly measure the expulsion of a magnetic field from the samples — an unambiguous signature for superconductivity called the Meissner effect that has never before been convincingly demonstrated in a superhydride. Curiously, the sample also shifted in color from blue to pink to red in sync with its phase changes.
The paper’s plots are exactly what researchers look for when they test for superconductivity. The strong evidence thrills many scientists who have spent decades searching for materials that can bring the phenomenon closer to everyday conditions.
“I am really excited to see the result. And I don’t in any way doubt that what they’re observing is what it is,” said Siddharth Saxena, a physicist at the University of Cambridge who was not involved in the new work. Eva Zurek, a theoretical chemist at the University at Buffalo who often communicates with the Rochester group but who was also not involved in the research, said that a material that superconducts under these conditions “would impact every aspect of our life in ways we cannot imagine.” Hamlin agrees that the demonstration “is a tour de force of every kind of measurement you would want to see on this material, producing exactly the type of data you would hope to see.”
A Troubled History
Yet Hamlin and other researchers insist that the group’s past requires that today’s historic claims be met with historic levels of scrutiny.
“There is a lot of evidence for superconductivity here if you take it at face value,” said Jorge Hirsch, a physicist at the University of California, San Diego. “But I do not believe any of what these authors say. I am not sold at all.”
Hirsch said his mistrust stems from a long history of allegations of research malfeasance made against previous and current members of the group, many of which he has pressed. Most recently, in 2020 Dias and his co-authors published a study of a carbonaceous sulfur hydride (CSH) that hit its critical transition at around 14 degrees Celsius (57.2 degrees Fahrenheit) and 267 gigapascals. Almost immediately, a handful of experts spotted unusual patterns in the data used to verify the material’s response to magnetic fields. When Dias and his frequent collaborator, Ashkan Salamat, a physicist at the University of Nevada, Las Vegas released their raw data a year later in the form of a 149-page document, they detailed an unusual and complicated method for eliminating background magnetic interference — one they said was necessary for them to detect the tiny magnetic field rejected by the small sample. This method was inconsistent with how they’d described the procedure in the original paper, which led Nature to issue a retraction last September.
Hirsch and other physicists allege that the misconduct goes beyond a misleading mix-up regarding the magnetic background. In September, Hirsch and Dirk van der Marel, a professor emeritus at the University of Geneva, published a claim that what Dias and Salamat had released as raw CSH data was actually derived from the published data. “[We] proved basically mathematically that the raw data are not measured in the laboratory; they are fabricated,” Hirsch said. Hamlin independently released a preprint last October claiming that the electrical resistivity data also appeared to have been processed in an undisclosed manner — a new allegation atop the issue that led to the 2022 retraction.
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Ranga Dias in his laboratory at the University of Rochester.
J. Adam Fenster/University of Rochester
Dias defends his work vigorously. In the months since the retraction, Dias has conducted additional experiments on the CSH material at Argonne and Brookhaven National Laboratories. In these, he invited independent scientists to observe the material’s superconducting transition. He recently submitted a new manuscript to Nature that repeats the claim of high-temperature superconductivity in CSH with rigor he insists will dispel past allegations.
“The witnesses to our work attested to our discovery. We have demonstrated CSH works to achieve superconductivity, as does ‘reddmatter,’” Dias said, referring to the group’s informal, Star Trek–inspired name for the new lutetium-based material. “You can either believe the evidence or not — but you can’t ignore it.”
Nilesh Salke, a physicist at the University of Illinois, Chicago who assisted with the new measurements and was not involved in the 2020 research, said that “the new work confirms the superconductivity in CSH.” He called the discovery of the new lutetium material “remarkable,” adding that it’s “an important milestone in the field of superconductivity.”
Yet the CSH paper isn’t the only related work under fire. One co-author of the CSH paper, Mathew Debessai, was the first author on a 2009 study claiming superconductivity in a third material, europium, which was later retracted for presenting altered data. (Dias was not a co-author of this paper.) Hirsch asserts that in that publication, “the data are copied and pasted into another region.” Others have also argued that some of the data in another of Dias’ recent papers was duplicated from data taken while the team was studying a completely different substance.
I am really excited to see the result. And I don’t in any way doubt that what they’re observing is what it is.
Siddharth Saxena, University of Cambridge
Dias strongly denies all allegations of wrongdoing and continues to make efforts to rigorously establish his claims of finding superconductivity at everyday temperatures and what counts as almost-everyday pressures in the high-pressure physics community. He stresses that today’s paper describing low-pressure superconductivity in the lutetium material underwent an unusually rigorous peer review process involving multiple rounds of review over the better part of a year. Dias also said that he shared all of his raw data with Nature, and that it will be published alongside the new result. Multiple independent experts voiced confidence in Nature’s ability to make sure that the result was as rigorous as possible.
“I am pretty sure the Nature editor and reviewers must have grilled them before giving a green signal,” Salke said.
“For me, it is difficult to imagine a second retraction,” said Mikhail Eremets, a physicist at the Max Planck Institute for Chemistry in Germany who led the discovery of hydride superconductors. “We should consider it seriously in spite of the prehistory.”
Dias emphasized that he and his colleagues have been completely transparent during an extraordinarily thorough review process. “This time we gave everything,” he said. “All the techniques and everything. Reviewers had access to all the data.”
The remarkable review process, when layered over an uncertain history, has left some researchers in limbo. “I don’t know anymore what I can believe,” van der Marel said. “That’s the whole problem.”
Confirmation and Commerce
Ultimately, acceptance by the wider community of researchers will lie in the hands of other labs. Will they be able to reproduce the material and confirm its superconducting properties? There are reasons to hope that an answer will come relatively quickly.
While there are only a handful of groups in the world who could work with the incredibly high diamond-anvil pressures needed to see superconductivity in CSH, there are dozens of labs that can work in the lower-pressure regime of the lutetium-based material, Hamlin said. Dias said that in the past few months, his lab has been working on a way to remove the diamond anvil cells from the process entirely, which could further speed efforts to confirm the finding.
To allow other labs to faithfully reproduce the results, the group must be willing to share their entire raw data set along with detailed sample-preparation methods, or to send samples of their material to other labs to test, said Hamlin.
However, outside access may fall short of the community’s hopes. Dias and Salamat have founded a startup, Unearthly Materials, which, Dias said, has already raised over $20 million in funding from investors including the CEOs of Spotify and OpenAI.* They’ve also recently applied for a patent on the lutetium hydride material, which would deter them from mailing out samples. “We have clear, detailed instructions on how to make our samples,” Dias said. “We are not going to distribute this material, considering the proprietary nature of our processes and the intellectual property rights that exist.” He suggested that “certain methodologies and processes” are also off the table.
“Without breaking any IP laws, we’re happy to share what we did,” Dias said. “There are some limitations as well, but I think we can work out something.”
In a 2021 talk organized by the Sri Lanka Association for the Advancement of Science and later posted to YouTube, Dias said “We recently raised $20 million just to, you know, focus on the science part of this. And these are the investors that we used for this kind of technology.” At that moment (43:25 in the video) a list of names appears on the screen. Under the category labeled “Investors (Series A),” the names include Sam Altman, CEO of OpenAI, and Daniel Ek, co-founder and CEO of Spotify. Following the publication of this article, a representative for Dias told Quanta that those were “aspirational statements,” that the company had not raised the money, and that the names listed were prospective investors.
Correction: March 8, 2023
The original version of this article identified Nilesh Salke as a postdoctoral researcher. In fact, he is a research assistant professor.