Monday, March 23, 2009

Bronze

This is an excellent history of the bronze industry of the Bronze Age in Eurasia. Not unexpectedly, it fails to integrate the Bronze Age of the Americas at the same time. The acceptance of the reality of the Atlantic trade has not happened yet, no matter the climbing mountain of evidence. I suspect that every possible copper source around the globe that was accessible was exploited.

Again, if a Bronze age mining clan could exploit copper grades of a miserable eight pounds to the ton in Ireland and all the man hours of wood cutting, charcoaling, rock breaking, grinding, metal separation and smelting that that implied, then getting on an open boat to travel across the Atlantic was paradise.

Much of the conjectures that I have made earlier regarding the economic importance of copper are richly confirmed in this work. I have little to add.
There is a good comment linking the heroic image of the smith from Greek mythos to its clear Bronze Age origins. Arsenic was an occupational hazard that likely wreaked most in the trade. That also explains the popularity of tin. Not because the result was particularly better, but because the smith survived repeated exposure.

Anyway, this is a very complete survey and updates earlier work.

Bronze

Once skilled smelters could extract copper from sulfide ores, copper became much more plentiful as a metal. Eventually, however, smiths realized a new paradox: the most valuable product from these new ores was not pure copper, but a range of new substances that contained impurities.

In nature, chemicals are hardly ever pure. No wedding ring is pure gold, and no natural water is pure. Copper ores are never pure either, and all smelted copper contains impurities. The ancient smiths who exploited the first easy native-copper nuggets, and the dramatically colored surface malachite and azurite carbonate ores could select relatively pure ores for their smelters, and they did not have to worry too much about impurities in the copper that they produced. But as demand rose and the first early ore discoveries were worked out, they mined deeper, and began to reach copper sulfide ores that were more difficult to smelt and less pure.

The "copper" that began to come from the smelters now had relatively more impurities in it. Smiths were inadvertently smelting batches of metal that were not pure copper. Each batch was now an alloy, a metallic substance that is not a chemical compound, but a physical mix of two or more metals that may act as if it were a different metal. In our modern hardware stores, for example, we can buy solder (an alloy of tin and another metal [often antimony] which doesn't behave like either of them).

Almost all copper ores contain some small proportion of arsenic, tin, zinc, antimony, or nickel, which mixes at the molecular level with the copper during smelting‹in other words, a tremendous number of subtly different alloys can emerge out of a smelter after a mixture of ore has been smelted, even though the geologist has been skilled enough to select ores that are rich in copper. The alloys are still dominated by copper, but the alloy has a lower melting point than pure copper, which allows easier melting and casting. The castings are better quality, and the alloy is much harder than pure copper after it has been worked by hammering. Paradoxically, the less pure copper ore that was available, the greater the variety of alloy the smith would produce from his smelter. By trial and error, early metallurgists (smiths) would soon come to associate a particular mixture of ores in the furnace with a particular result. In time, a skilled smith would be able to have some control over the end product, producing not copper, not a random unknown alloy, but a specific alloy to suit the job at hand. The Bronze Age marks the time at which smiths became metallurgists, makers of magic, heroes, and gods. Bronze Age smiths were often buried with the tools of their trade: hammers, an anvil, knives and molds.

Bronze is any alloy that is 85-95% copper, with the other 5-15% made up of mainly of tin or arsenic, though other metals can be present in small amounts. It turns out that this range of chemistry produces an alloy that is harder than copper even though it melts at a lower temperature. A low amount of tin or arsenic does not improve the copper enough, and a higher amount makes the alloy so brittle that it is useless. Tin bronze is not too difficult to work, and melts at 950 degrees C rather than the 1084 degrees C of copper, making it easier to cast. Both bronzes make strong hard tools and weapons that retain an edge as well or better than stone, once they are strengthened by hammering. Other metal alloys were not available to bronze-smiths. Zinc (which alloys with copper to make brass) or nickel are rarer and much more difficult to smelt, and antimony/copper alloys are brittle.

In the Chalcolithic period in which copper and stone artefacts co-existed, we can see smiths producing bronzes, without realizing what they had done, and without using the bronze to its best advantage. For a long time, smiths used copper of greater or lesser purity without much discrimination. For example, many early Chalcolithic objects are made from copper with more than 5% arsenic. They were not made with the properties of arsenical bronze in mind, however, because there is no correlation between the object and the arsenic content: tools are made with low-arsenic copper and ornaments are made with high-arsenic copper. Probably arsenical copper was used only because arsenic lowered the melting point and made casting easier.

When and how were the mechanical properties of bronzes deliberately produced by smiths? I expect that at first, a skilled smith would be able to sense the different properties of each batch of metal that came from the smelter, and would keep the rough ingots arranged by property. He would quickly find that bronzes varied in hardness along a scale, with the optimal balance between softness and brittleness at 5­10% tin/arsenic. It's not that he had a chemical analysis, but he had a feel for hardness as he hammered the hot ingot. Once he was that far into the analysis, it would be an obvious step to combine two ingots at the ends of the scale to try to mix them into the best-quality alloy in between, and he would discover that the process worked as long as he melted then together completely. From that point, the smith with the best analytical skills (his touch with the hammer) would be able to produce the best artefacts.

At some point, a smith would connect the properties of the bronze ingot with the properties of the ores going into the smelter, which would save him a lot of work and charcoal blending ingot together. At this point the smith is truly master of his craft, and one can easily imagine that the best smiths would have routinely produced bronzes of much higher quality than normal. Smiths take on legendary or god-like form for the first time.
Arsenic ores are more common than tin ores, and make high-quality bronzes: there are no tin bronzes in Western Asia before 3000 BC. Arsenic bronzes do not cast as well, but are as hard as tin bronzes. The choice between arsenic and tin bronze may not have been easy, even when it became available. The choice may have depended on the ores available locally: arsenic/copper ores are common, while copper/tin ores are rare. We don't know accurately how often arsenate ores occur in copper deposits because the question is not important in modern mining. In this case, it is just possible that Chalcolithic miners were better informed than we are!

After 3000 BC, Cretan and Western Mediterranean bronzes were largely made with arsenic, Egyptian bronzes almost exclusively with arsenic, but Anatolian bronzes were made with both. We suspect that Anatolian bronzes were first made with tin extracted from the mineral stannite. It is difficult to distinguish tin-bearing stannite from the arsenic-bearing minerals arsenopyrite and enargite. Possibly the first use of tin ores stemmed from a simple mistake by prospectors searching for more arsenic-bearing ores.

Eventually smiths turned to tin ores even though they were more difficult to obtain than arsenic-bearing ores. Smelters work outside, so fumes can be dispersed in the wind, but a smith cannot help breathing in arsenic fumes as he heats, casts, and hammers hot arsenic-laced bronze. The symptoms of low-level arsenic poisoning develop slowly, usually over a period of years. The most obvious symptoms are gradual nerve damage in the limbs. Eventually smiths must have realized what was happening to them, and what was responsible; and eventually they recognized the danger of working with arsenic alloys. Except in Egypt, where arsenic was used until 2000 BC, tin bronze gradually became the alloy of choice, and the dominant metal of advanced civilizations in the Western World for 2000 years. The long agony of so many Bronze Age smiths has come down to us in legend, however: the Greek smith god Hephaestus and his Roman counterpart Vulcan were lame. This is not an occupational hazard of the Iron Age smiths that forged spears for the Greek hoplites and swords for the Roman legionaries. It reflects the centuries-old folk memory of their predecessors.

Bronze gave its name to the Bronze Age, a major innovative period in human history. Bronze artefacts are found at Ur and other Mesopotamian cities after about 3000 BC, then all over the Near East. A "bronze age" can only occur where copper and tin are both available, where the mining and smelting technology are developed, and where trade networks can disseminate the new technology and the new artefacts. Many regions did not have a bronze age, but changed directly from Chalcolithic to iron use.

The Source of Tin for the Bronze Age

Until 1984 we did not know the source of tin for the ancient bronze civilizations of the Near East. Now more than 40 ancient sites of tin mining have been discovered in the Taurus mountains of southern Turkey, only 40 km from the Cilician Gates, the main pass through the Taurus. The area has a great variety of metal ores, including placer deposits of gold and silver. But lead (as galena) is also present, and lead artefacts are known from Çatal Höyük. Cast lead figurines had become common by the late third and early second millenia, and silver was important from the late fourth millennium.

Cassiterite, the dominant tin ore, is tin oxide. It occurs as distinctive black grains in alluvial sands, and in some areas it is left behind as a resistant mineral after granite has weathered down to sand and clay. It is possible that its properties were examined closely by potters: kaolinite deposits often occur around old granite bodies, and cassiterite grains could be caught up in potters' clay. Since cassiterite melts at only 600 degrees C, it would be noticed, and perhaps accidentally smelted to tin.

An ancient tin mine was discovered in the Taurus at a site named Göltepe, which was a large village from around 3290 BC to 1840 BC. The mine has narrow steep shafts, and at least some of the underground work may have been done by children (several skeletons of children have been excavated from the mine). Cassiterite ore was then crushed at the surface, washed, and smelted with charcoal in rather small crucibles rather than the large furnaces characteristic of copper smelting sites. Goltepe has yielded many crucibles in which the tin was smelted into a slag that contained globules of pure tin, which had to be separated out by crushing and re-washing. The small scale of the crucible operations, and the crushing of the slag for multi-stage refining, make it difficult to detect the scale of the operations. But since over time the industry produced enormous deposits of slag in the district (600,000 tonnes in one pile), Göltepe was probably a major site for much of the Early and Middle Bronze Age. Some of the slag may date from more recent times, at least some of it is ancient, and some of it is very rich in tin.

The Taurus mountains, then, probably provided the tin for alloying into the earliest tin bronzes of the ancient Near East. There is no copper at Göltepe, and the tin was clearly exported to other centers for making bronze. However, other cities close by were centers that were famous for metal trading and metal working in the second millenium BC: Kültepe and Acemhüyük.

Metal traders and imperialists

After about 3500 BC, there was increasing use of several metals in Mesopotamia, not just copper and lead. Gold and silver were exploited as native metals. Silver was extracted from lead ores, possibly first as a by-product of lead, then as a desirable commodity in its own right. Bronze appeared in the region about 3000 BC.

The metal-working found in the royal tombs of Sumer (about 2650­2500 BC), whether it was done locally or was imported, is breath-taking in its beauty and skill. Riveting and soldering were invented, and by 2500 BC the value of tin was well known for soldering and brazing. Casting techniques were good enough to make human-sized statues and small lost-wax figurines.

Metal began to play a part in international relations, especially during Akkadian times (2350­2200 BC). About 2350 BC Sargon of Akkad invaded Anatolia from his lowland base. He set up a short-lived empire of secure trade routes, and he boasts that a single caravan carried about 12 tonnes of tin, enough to make 125 tonnes of bronze‹and to equip a large army.

After the fall of Akkad, the Assyrians ended as the dominant power in what is now northern Iraq. We have known for a long time that tin was brought in to Kültepe, in Anatolia, by Assyrian merchants and sold to local metal workers at prices that are recorded on local tablets as very high. A major trade in tin is recorded in Old Assyrian letters from about 1950-1850 BC. Tin shipments were sent on donkey caravans from the Assyrian capital, Assur, to Assyrian merchants living in Kültepe, who sold it to the local smiths, presumably for bronze-working in and around Kültepe. The shipments record well over a tonne of tin per year, enough to make about 10­15 tonnes a year of bronze.

This trade is subject to several interpretations, of course. The most likely is that foreign tin was imported to the processing area as local ores ran out, in the same way that South American tin was shipped to South Wales after the Cornish tin mines could no longer supply enough to the tinplate industry. (Today the British steel industry depends on imported iron.) Probably tin, the smaller and scarcer component of bronze, was shipped into Kültepe because the district was rich in copper, fuel, and technological skills, even after local tin ores were mined out. This policy would certainly make economic sense for the smiths of Kültepe, even if they had to import the tin to keep their bronze industry going. Presumably the Assyrians bought much of the bronze, though this is not recorded in the letters: the tin was sold in Kültepe for silver or gold. Kültepe by this time may have been very much a "smokestack" city, working bronze but with the profits skimmed off by the politically dominant Assyrians. (The letters indicate that the tin was marked up 75­100% between Assur and Kültepe, while transport costs were about 10% of the price in Assur.) Certainly any wealth from the industry did not support the same glittering power at Kültepe that is seen often in Bronze Age centers, though the Assyrian merchants in Kültepe were buried with gold and silver ornaments!. By 2000 BC Kültepe was an industrial city: political power was elsewhere.
Tin must have been a very important strategic metal, even though bronzes could also be made with arsenic, at great occupational hazard for the smelters and smiths. All around the Mediterranean, copper and tin mining were dramatically stepped up in this period.

Timna: Bronze Age mining and smelting

The Chalcolithic copper mining district at Fenan in the southern Levant was expanded in the Bronze Age‹major workings began some time between 3000 BC and 2000 BC. The most famous sites are in the Sinai desert, and at Timna near Eilat, but others stretch from the southern Sinai to northern Israel and Jordan. There are more than 300 sites near Timna alone, and over 400 in the Sinai Peninsula.

The Timna workings are some of the best-studied industries of the Early Bronze Age, typical of the entire desert copper-mining and smelting operations, even though the quantities mined were small, even by the standards of the time. The miners at Timna were digging for nodules of malachite in fairly soft sandstone. They used hafted stone hammers, digging vertical shafts connected by galleries. The shafts and galleries were rather haphazard, presumably following rich ores without any overall plan. The ore preparation sites contain broken pieces of malachite copper ore, granite mortars and pounding stones, other stone tools, and pottery shards. The smelting furnaces were not on the valley floor, but high on the ridges, so that the wind would help raise the furnace temperatures by forced draught. Pieces of slag are scattered round the furnaces, some containing little blobs of metallic copper created in the furnaces. The furnaces themselves are bowl-shaped, with a clay layer lining a sandstone cavity about 80 cm (nearly 3 feet) high. The fuel was collected from the desert acacia trees in the region, and fuel shortage was probably the main reason for the rather small production from Timna.

Experiments show that the Timna furnaces reached temperatures between 1180° to 1350°, which could only have been achieved with some forced draught other than natural wind currents. Perhaps goatskin bellows were used. Charcoal makes a hotter fire than wood, and may have been used also. The Timna furnaces produced rather impure masses of metal that needed further cold working by hammering, or a further firing to produce much purer copper ingots. (Later technology, with larger furnaces and hotter fires, allowed smelting to be carried out in one step.)

At Fenan, which was mined for copper in Chalcolithic times (Chapter 3), Bronze Age workings began around 2000 BC. The Fenan miners now followed the ores far underground, in inclined shafts that were as much as 15 to 20 m underground and at least 55 m long. The ore-bearing layers were carefully mined on a chamber-and-pillar system, with pillars left to support the roof. The best ore was separated from waste rock underground by lamplight, and the waste either packed into old galleries, or piled up into artificial support pillars, with the addition of large boulders dropped down from the surface from the bed of the wadi. These methods exploited the ore efficiently, avoiding the labor of carrying too much material up out of the mines.

Bronze Age production at Fenan has been studied only superficially. Fenan production was large, and it must have been a strategically important area. The copper was eventually worked into very finely executed objects, many of them ornamental pieces that presumably had high value. Copper objects were traded and hoarded at this time all over the region from Anatolia to Egypt and Mesopotamia.

Timna under Egyptian management

The best documented history of technological advance in early smelting methods comes from Egypt, where pictorial images flesh out the written record. The Egyptians brought new technology to the malachite workings at Timna around 1300-1100 BC, where the local Midianites worked at least eight large mining centers along the Timna cliffs, using bronze tools. It's clear that Egyptian copper- and gold-mining technology had its roots in mining methods that were originally designed to mine for turquoise in the Sinai peninsula.

The smelting centers nearby were highly organized, with areas for ore crushing, storage pits for ore, charcoal, and iron oxide flux. Scores of furnaces were clustered close together, this time on the valley floor rather than on the ridges, because the Egyptians now relied entirely on bellows to pump air through the furnaces. Each furnace was sunk into the desert sand, and was lined with cement. Each had one or more complex tuyères in it, nozzles to which a bellows were connected.

The copper was sent off to Egypt to be made into bronze: tin bronze by this time. Copper and tin ingots were melted together in the right proportion, and the molten bronze used to make the desired objects. These were sometimes as large as temple doors. The Sinai mines were not the major source of copper for ancient Egypt, however: there was extensive trade with Cyprus, too.

Cyprus

Cyprus has extraordinary copper deposits that were mined in ancient and classical times: the name for the metal in all Western European languages is derived from the Latin aes cyprium which means "Cypriot copper."

Once smelting of sulfide ores became economic from about 1600 BC, Cyprus became a vital link in the trade of Eastern Mediterranean Bronze Age cultures for 500 years, serving not just as a convenient island in the center of many trade routes, but producing large quantities of copper for export. Every major copper body mined in the early 20th century in Cyprus had already been discovered and mined in ancient and/or classical times. Altogether, Cyprus has more than 40 slag heaps containing more than 4 million tonnes of historic slag, showing the massive scale of the industry over time.
Homer says that his heroes wore Cypriot bronze armor in the Trojan War (about 1100 BC?). The Cypriots used copper and bronze to pay debts and tribute: for example, about 1470 BC the ruler of Cyprus paid tribute to Pharaoh Tutmose III with 108 ingots of copper. The ingots weighed about 30 kg (65 pounds), and were poured into molds that resemble ox-hides‹a rectangle with four projecting corners. The size of the ox-hide ingots means that furnaces had reached much larger size than those at Timna a few centuries before: the ingots are ten times as big. The shape is probably convenient for pouring and handling, rather like the "pigs" of later iron-workers, but it may also refer to the bull-worship of the region. Ox-hide copper ingots have been found all over the Mediterranean shoreline, reflecting two facts: first, that most large-scale trade was shipborne; and second, that copper ingots were an acceptable form of currency. A shipwreck from about 1300 BC, discovered at Ulu Burun, near Cape Gelidonya on the Turkish coast, was carrying a tonne of copper ingots and several dozen small tin ingots, new bronze tools, and scrap metal, and a blacksmith's forge and tools. Thus the cargo of one ship could have equipped the army of one of the small Mycenean city-states: 50 suits of bronze-sheathed armor, 500 spear points, 500 swords. This ship was also carrying enough valuable gift goods (ivory scepters, shell rings from the Red Sea, and a complete ostrich egg) that excavators are beginning to suspect it may have been carrying a diplomatic mission along with its cargo of strategic weaponry (probably not a new concept in international politics).

Copper and bronze were precious enough that old artefacts were recycled. (A Middle Babylonian document says that if a slave escaped with his copper chains, the guard responsible would be charged twice that amount in copper. In other words, the chains were valued as much as the slave.) Smithies were often as much recycling centers for old bronze tools as they were centers for alloying new copper and new tin into bronze. Archeological sites often contain as much scrap bronze as they do new ingots.

Copper and Bronze in Central Europe

Trade in copper was not confined to the Mediterranean, of course. About 2500 BC copper began to be produced from centers in Germany and the Carpathians. By 2000 BC, the bronze industry had percolated throughout Europe, and regional smiths made their own distinctive products. Deep gallery mines in the Alps, in Bohemia, and in the Carpathians produced copper ores, and bronze really began to displace stone for the first time in everyday tools during this period. The best studied are mines in the Mitterberg region of Austria, which had systematic galleries 150 m long that followed ore bodies, interconnected in some places by galleries that must have been for better air circulation, for the sake of fire-cracking as well as the health of the miners. Wood and clay dams kept water from flooding the working faces, but even so, there were water problems, and many pieces of wooden buckets have been found. Many thousands of tonnes of copper were produced during the thousand years of the Bronze Age in this part of Europe: some of the slag heaps have up to 500 tonnes of slag, and there are hundreds of them. Copper ingots were mass-produced, and were cast into characteristic shapes, rings or curved bars. Thousands of them have turned up in ancient copper hoards, many hundreds of kilometers away from the mines.

Bronze in China

The earliest well-dated bronze object in China is a knife from Gansu province, from about 3000 BC; it had been cast in a mold. There are smelting sites nearby with malachite ore, slag, and corroded copper. Somewhat later, the Qijia Culture of north China was producing a good number of copper and bronze awls, knives, sickles, and adzes, using casting techniques followed by cold-hammering to harden them. In 1976 copper and bronze artefacts were found in Gansu province associated with the Xia Dynasty, which on other evidence is dated from 2200 BC to 1760 BC. All the evidence, then, suggests an independent Chinese discovery of bronze (tin is comparatively abundant in China).

Bronze became widespread in the central plain of China in early Shang times. The Shang dynasty ruled from its capital at modern Anyang, in Henan province, for 300 years until its collapse in 1122 BC. Anyang was close to the most abundant deposits of lead, copper, and tin in China, and bronze-making apparently spread from here to the rest of China. Shang metallurgists had discovered that a small percentage of lead in the bronze made casting easier. They produced ceremonial cast bronze cups and bowls of all sizes up to massive cauldrons, intricately decorated with raised or incised relief designs taken from nature. The largest Shang cauldron weighs 875 kg (nearly a ton), and is the largest metal casting from anywhere in the world from the second millenium BC.

Casting large objects is not easy. It requires large crucibles and efficient furnaces, and casting the largest objects requires coordinated melting in many crucibles that resembles a modern factory.

A problem with the quality of the Shang bronzes is that they are so impressively large, leading some scholars to feel that somewhere else there must be an earlier bronze-working culture still to be discovered. However, the Shang metallurgical tradition probably arose very quickly from pottery making. The Chinese made porcelain in Neolithic times: pottery kilns found near Xi'an were designed to maintain temperatures as high as 1400 degrees C as early as the 6th millenium BC, more than enough to melt copper. Many of the ritual Shang cups and crucibles, including their ornamental relief, are shaped in direct continuity with earlier clay objects. Shang metallurgists did not use stamping, or engraving, or hammering in their work: they simply cast their works of art. Probably, then, the Shang used casting methods almost exclusively because their pottery industry was so advanced they could readily reach the high sustained temperatures that made smelting and casting comparatively easy. The Western tradition of hammering metalwork and the Chinese tradition of casting it (at least from Shang times onward) are in stark contrast. .

The Chinese became more sophisticated bronze metallurgists than their Western counterparts. The famous terracotta army of the Emperor Qin, made for him about 220 BC and buried with him, have weapons that are basically bronze, but they have been deliberately alloyed with metals such as titanium, magnesium, cobalt, and so on, no doubt after empirical trial and error, to give superior hardness and penetrating power. This weaponry, combined with technological advances such as fast-loading crossbows, united China under the Qin dynasty and defended it against invaders.
Other Chinese bronzes, designed for other purposes, have lead alloyed to improve casting fidelity and to make polishing easier. These alloys were used to make bronze mirrors and bells. In 1978, 64 bronze bells were found in the tomb of a nobleman named Yi, dating from about 450 BC. The largest bell weighs 203 kg (about 450 pounds), and is 1.5 m (over 4 feet) tall. The bells together allow a complete 12-tone scale to be played by a team of five to seven musicians.

Overall, the Chinese bronze industry was very large: an enormous mine dating from around 400 BC has been excavated at Tonglushan: it covered an area of 2 km x 1 km, and had deep timbered underground galleries.

Mining, Smelting, and Fuel

Once copper smelting developed from pottery-making, the use of wood fuel accelerated. By the time the Bronze Age was well under way, wood was being consumed around the Eastern Mediterranean on a scale that could not possibly be sustained on a long-term basis. Mining, smelting, metal-working, ship-building, pottery-making, and construction industries all had massive appetites for fuel, and almost all domestic fuel was also wood.

As cities developed around the seasonally dry eastern Mediterranean, they had to build large cisterns for water supply; most often their construction demanded large quantities of cement and plaster. Mediterranean private and public buildings all contained large quantities of cement, plaster, brick, and terracotta, all of which required far more wood for production than the equivalent amount used directly for construction. The effects on local fuel supplies would have been increasingly severe.

Egypt, which has practically no trees, was trading with Byblos (on the Lebanese coast) for cedar for shipbuilding, temple construction, and furniture-making as early as 3000 BC. But perhaps the most famous documentation of the shortage of wood around the ancient Mediterranean is the Epic of Gilgamesh, the earliest epic poetry that has survived. Gilgamesh was a Sumerian, king of Uruk around 2700-2500 BC. He conquered Kish, Uruk's great rival city, thus gaining power over all of southern Mesopotamia. Apparently the first epics about him were written in Sumerian around 2000 BC. We do not have the originals, but we have copies made by scribes in Old Babylonian times for their libraries. They were separate stories, and the welding of these separate pieces into an Epic was an Akkadian literary innovation, not a Sumerian one. This means that the central theme of the Gilgamesh epic may date to 1500 BC rather than Sumerian times, but it is still illuminating.

Stripped of sex and violence, the Gilgamesh epic is about deforestation. Gilgamesh and his companion go off to cut down a cedar forest, braving the wrath of the forest god Humbaba, who has been entrusted with forest conservation. It's interesting that Gilgamesh is cast as the hero, even though he has the typical logger mentality: cut it down, and never mind the consequences. The repercussions for Gilgamesh are severe: he loses his chance of immortality, for example. But the consequences for Sumeria were even worse. It's clear that the geography and climate of southern Mesopotamia would not provide the wood fuel to support a Bronze Age civilization that worked metal, built large cities, and constructed canals and ceremonial centers that used wood, plaster, and bricks. Most timber would have to be imported from the surrounding mountains, and deforestation there, in a climate that receives occasional torrential storms, would have led to severe erosion and run-off. The loss of Gilgamesh's immortality may be a literary reflection of the realization that Sumeria could not be sustained.

Theodore Wertime suggested that massive deforestation of the eastern Mediterranean began about 1200 BC, for construction, lime kilning, and ore smelting. Probably it began earlier in the drier regions further east. King Hammurabi's laws (around 1750 BC) carried the death penalty for unauthorized felling of trees in Mesopotamia. The problem may have been even worse in intensive metal-working regions like Anatolia. Metal smelting and forging had been going on in Anatolia for at least 3000 years by 1200 BC.

At any rate, most likely the Bronze Age saw a westward spread of a timber crisis. By 800 BC an extensive new use (ornamental and roof tiles) added to the burden, and around 500 BC the rise of the classical civilizations brought the final intolerable strain on the forests immediately round the Mediterranean. Eratosthenes, writing of the Late Bronze Age, say 1200 BC, reports that Cyprus was so heavily forested at that time that even smelting copper and silver, and felling trees for shipbuilding, had made little inroads on the forest. Farmers were even encouraged by gifts of land to clear the forest for agriculture. But soon after this a boom in mineral production, and a major improvement in the technology of tree-felling tools (as well as military weapons) both allowed and encouraged major forest clearing.

The great silver mines of Laurion, near Athens, required not only the fuel to smelt the ores, but the fuel to build and maintain the water cisterns. Wertime estimated on the basis of 3500 tonnes of silver and 1.4 million tonnes of lead production for classical Athens over perhaps 300 years, that the Laurion mines had consumed 1 million tonnes of charcoal and 2.5 million acres of forest. It is, in fact, quite likely that the mines declined, not because they were exhausted of ore, not because the miners had reached the water table, but because the fuel costs had risen to the point that they were uneconomic to run. It is clear that deforestation, accompanied by soil erosion, was already a severe problem in Attica, the region surrounding Athens. Plato wrote that the region is a mere relic of the original country.... What remains is like the skeleton of a body emaciated by disease. All the rich soil has melted away, leaving a country of skin and bone. Originally the mountains of Attica were heavily forested. Fine trees produced timber suitable for roofing the largest buildings: the roofs hewn from this timber are still in existence.

Shipbuilding timber had to be imported from the Balkans and southern Italy to build the great Athenian fleet that beat the Persians at the Battle of Salamis in 480 BC. Timber was a vital strategic commodity during the Peloponnesian War between Sparta and Athens. In 422 BC the Spartans conquered the Athenian trading cities on the coast of Macedonia. This alarmed the Athenians greatly, because it cut off their gold supplies and their ship-building timber, which had been shipped down the coast from the inland forests of Macedonia. By 415 BC Alcibiades of Athens was arguing for a major expedition to try to seize control of Sicily because of the supplies of timber there‹and the failure of this expedition was the critical point at which Athens lost control of the war and went down to defeat.

[A similar situation faced the British during the war against Napoleon. Napoleon had ordered an embargo on trade with the British, and in 1801 the French armies controlled Denmark. The Danes controlled seaborne trade with the Baltic Sea, because all ships had to pass by Copenhagen on their way out through the Kattegat into the North Sea. The Baltic trade was vital for the British because it provided them with their only supply of fir trees for ships' masts for the Royal Navy. (The American colonies, with their vast forests, had been lost in 1783 or 1776, depending how you like to count it.) The British fleet bombarded Copenhagen, destroyed the Danish fleet, and opened that vital strategic route. History might have taken a very different turn if the British had failed. It was close. Admiral Nelson ignored orders to withdraw (by putting his telescope to his blind eye) and pressed home the critical attack on the Danish fleet.]

The crisis in wood continued to plague Athens. By 313 BC the only available ship timber in or close to Greece itself was in the far northern forests of Thrace and Macedonia: overseas supplies had to come from the Black Sea coasts, southern Turkey, Lebanon, or Italy. By the 4th century BC it was no longer economic to transport charcoal overland and uphill to the mines at Laurion: instead, the ore was smelted down on the coast, and charcoal was shipped in on barges. Even then, an increase of lead content in the slag shows that the smelting was being done with minimum fuel.

The island of Elba was once called Aethaleia, "the smoky island," because of the massive smelting industry there. But the Romans had to give up smelting ores from Elba on the island itself in the first century BC because they ran out of wood: they had to ship ore to Populonia on the mainland to continue the industry. By late medieval times, even the productive forests of Germany could usually support iron smelting for only three months a year.

The Rio Tinto mines in Spain probably needed 260 tonnes of wood a day even in Roman times. Fuel shortage may have been the single most serious constraint on copper production as early as the Bronze Age in some areas.

Copper smelting needs a great deal of fuel, especially if the ore supply is dominantly sulfide. About 300 kg of charcoal are needed to produce 1 kg of copper by smelting 30 kg of sulfide ore. A tonne of charcoal needs somewhere between 12 and 20 cubic meters of wood.

Archaeologists have estimated that the Bronze Age copper mines at Mitterberg, in the Austrian Tyrol near Salzburg, must have employed about 180 miners and smelters to produce about 20 tonnes of copper a year. Then one has to add the woodcutters, carpenters, charcoal burners, and carters who cut, carried, and processed the wood needed for the gallery timbers, the firing of the working face, and the fuel for the furnaces, and then add the farmers that fed all these. This was a very large-scale operation.

In copper smelting we find, perhaps, the first major environmental effect of mining. The Mitterberg copper mine probably required about 19 acres of forest to be felled each year, just for the smelters. Even with efficient natural regeneration of the forest, this is a sustainable harvest from perhaps 2 square miles of forest. In fact, however, the cleared land was probably used not for re-growth but at least partly for agriculture, to support the mining community.
On a time scale longer than 10 years, however, a Bronze Age copper mining operation must have caused local deforestation on a large scale, and ever-increasing costs for hauling the wood to keep the industry going.

The problem may not have been so great in the Alps, where there were smaller populations, and where the forest regrew comparatively quickly. But in the drier Mediterranean countries, there was an irreversible change in the vegetation and landscape. On Cyprus, the magnificent pine forest that once covered the island was cleared in a comparatively short time, mainly for charcoal for smelting. Cyprus has a classic Mediterranean climate with a long dry season, and winter rains on steep deforested slopes quickly degrade the soil by washing it downhill. Seedlings have difficulty in re-establishing the forest, especially after clear-cutting, and the soil quickly degrades to the point that pine forest cannot recover even by deliberate planting. Certainly the Mediterranean island of Seriphos has been deforested for a long time, although there are large copper slag heaps on the tops of the ridges, evidence of former forest and former massive wood consumption.

The tremendous tonnage of ancient copper slag on Cyprus suggests that the Cypriot copper industry collapsed around 300 AD simply because the island ran out of cheap fuel. The slagheaps suggest a total production of perhaps 200,000 tonnes of copper, and that in turn suggests that fuel equivalent to 200 million pine trees were cut to supply the copper industry, forests 16 times the total area of the island. Even given that high-altitude Cypriot forests can regenerate quickly in the right conditions, this suggests that wood fuel was a critical constraining factor on the Cypriot copper industry, and must have been a persistent problem on the island for other industries too.

The landscape of Cyprus today (and Greece, and Turkey, and Lebanon, and in fact most of the Mediterranean seaboard) is quite unlike its appearance 5000 years ago. The magnificent cedar forests of Lebanon were felled largely for timber for buildings and ships, but copper smelting must take most of the blame in Cyprus. This Mediterranean ecological disaster used to be blamed on the Arab introduction of goats to the region several centuries AD, but the change was much earlier. There are secondary effects of deforestation, of course: hillsides are exposed to greater run-off, and erosion can be greatly accelerated. Part of the story of the later Bronze Age seems to be the silting of coastal ports and cities. The city of Tiryns, for example, spent a great deal of effort just before its end building a diversion structure to keep floods out.

Page last updated April 1999.


Spring Bull Rising

The grimmest news is behind us in economic woes although we will be slapping patches on for the next few months. The global banking system has been shaken to their core and many of the banking elephants have become zombies. But we know all that and it is all now been priced into the market.

Most important, the Fed printed the coin to replace the depleted capital of the banking system. All those brokers are now working down the street at their smaller and wiser former competitors. And damn few of the brokers other that the five or so idiot corporations on Wall Street have folded.

That means that it is possible to have a rising market returning to health and all the positive things that go with that. Far too many very sound stocks are beaten down are will easily rebound, now that we are not fighting of waves of incredibly bad news.

I expect a major rebound in the energy industry in particular, led by the oils. We have entered the greatest industrial retooling since the Second World War. Everyone now knows that the USA must lead the world in shifting out of the oil paradigm to the alternative energy paradigm. Last year we discovered that oil priced over $100 is unsustainable. It is now recovering to the $50 to $75 range which is sufficient to keep it turning over. It is also sufficient to keep up the capital investment momentum in the total energy business.

All energy related stocks will be humming this summer and strengthening into the fall.

Nanosolar and EEStor may even make believers of us all.

Everything else will settle down and solve their hangover. This includes even Detroit.

I think that this past six months will be seen as one of the greatest directional changes ever seen in even the global economy ever. The financial dream machine has been shattered and must now slowly restore confidence. Retirements have disappeared and everyone is rolling up their sleeves to claw back their fortunes, much chastened by the financial tsunami that came through.

Amazingly, if you are free to act, and that is no small feat, it is the best of times.

Friday, March 20, 2009

Sarah Pallin is Presidental Timber

I have no doubt that we are going to see Sarah Palin run for the presidency and likely win the presidency. The lady has the right instincts, loves to tell stories and is sharp enough to be a quick study as demonstrated by how she decisively broke the political logjams in her own state. She is a communicator on the same level as Clinton and Reagan.

The fact that she is inexperienced in foreign affairs and in economic thinking is hardly a handicap, particularly when she has eight years to pick up the appropriate high level education. The only presidents who actually came to the job since Nixon fully prepared in those areas was Reagan and his vp George Bush in both economics and foreign affairs. Clinton was a fast study and Carter was not. The second Bush delegated for far too long and appeared to never grasp the enormity of what was happening. Obama is intellectually saddled with the fool’s gold of leftist economic theory as well as some of the more ardent believers. His thinking appears to be dangerously linear and this is not the time to mature intellectually. He will however, do very well on the foreign affairs portfolio because he seems able to make others to step down from confrontation. At least he is showing up with a bouquet of roses rather than packing for bear.

The political bashing of Sarah Palin has mostly run its course and that is now fading from people’ memories. And negatives cannot be used twice in politics to any effect. This means that her wonderfully powerful positive image that is unbeatable gives her the upper hand in any run for the presidency. Middle class America wants her and wants her to simply have a bit more experience which she will get over the next four to eight years.

Obama ended Hillary’s political hopes. Now his natural successor is standing in the wings.

Palin's Popularity Soars in Alaska

Thursday, March 19, 2009 8:19 PM

Alaskans aren’t fazed much by the ongoing Sarah Palin-bashing taking place in the Lower 48 -- a new poll indicates the governor’s popularity remains sky high among voters in her home state.

Anchorage-based pollster Hays Research Group says its March survey shows 61.3 percent -- nearly two out of every three Alaskans -- feel either “very positive” or “positive” about Gov. Palin.

Palin triggers a negative reaction from about one-third of Alaskans, however. The poll found some 32.7 percent of Alaskans rate Palin as either “somewhat negative” (12.5 percent) or “very negative” (20.2 percent).

Only 6 percent are undecided about her, suggesting that the GOP governor tends to evoke strong feelings one way or the other. The poll of 400 Alaskans has an error margin of plus or minus 4.9 percent.

Anchorage pollster Ivan Moore reported similar results in January. His survey showed Palin’s favorability rating at 63 percent.

Palin’s popularity has fallen well off her peak level of 89 percent. Palin reached that highpoint in an Ivan Moore survey conducted in May 2007, about 15 months before she was named GOP Sen. John McCain’s vice presidential running mate.

Eden Machine and the Great Central Valley

As I have posted, California’s central valley is prime country for terraforming with the Eden Machine. Reading this, it is obvious that their prime problem is actually water wastage of what they have. I do not have specific numbers, but it is a good be that 90 percent plus of the delivered irrigation water never passes through the plants.

And why field grown tomatoes when greenhouses wonderfully control water and nutrients?

The Eden Machine delivers water directly to the root system with almost no direct evaporation loss. This will also permit a natural buildup of ground water as the soils steadily increase their organic content.

It is also clear that ideally we need to start at the periphery of the drainage systems and slowly work our way inward. These are often beginning highlands and their restoration as active woodlands will capture and hold the sporadic rains. This will charge the ground waters around the central valley and ultimately alleviate the water issues of the valley itself.

I grew up in a river valley despoiled by the original pioneers and what had been lost was the core water retention of the valley bottoms in particular. The trees never recovered at all and the valley soils eroded away down to bedrock. All the winter snow washed out in early spring and the river became a trickle fed by the one intact swamp and small woodland.

Restoring natural water retention by using commercially valuable trees in combination with the Eden Machine in the remnant valley bottoms would be a best practice plan, even though the bulk will go to established flat land orchards, which will still release plenty of irrigation water.

Despair as California's Central Valley dries up

http://www.terradaily.com/reports/Despair_as_Californias_Central_Valley_dries_up_999.html


by Staff WritersFirebaugh, California (AFP) March 18, 2009

"Now we know how the Indians felt," sighed Jim Diedrich, a farmer who said he was betrayed by the government as California's Central Valley reels from a serious drought.

Diedrich, whose family has farmed in the western US state since 1882, bitterly surveyed their 640-acre (260-hectare) stretch of land.

What would usually be a tomato field has now been reduced to a dusty expanse dotted with weeds.

"We've got zero water this year," explained Diedrich, 66, who has spent 50 years working the land.

Like many other farmers in California, he had to leave idle most of his land in Firebaugh, 145 miles (230 kilometers) southeast of San Francisco. Gone are the 50,000 tons of tomatoes he would have sold for four million dollars.

The Central Valley, a vast expanse the size of Bulgaria, began as a semi-desert. But thanks to a massive irrigation network, it has become the number one source of market produce in the country: 94 percent of US tomatoes and 89 percent of US carrots are grown here.

But hit by a third successive winter of light rainfall, the lush desert miracle has gone awry.

"The storages are so low, the main population is number one, the fisheries,
wetlands, are second, and the farmers third," said Diedrich, explaining how the state-managed distribution system favors individuals and nature sanctuaries.

The coup de grace, he said, came when a federal judge ordered water pumping cutbacks from the Sacramento River Delta in August 2007 to protect an endangered fish species. Pumping was then cut by half, which exacerbated the water shortage.

Environmentalists are "very strong, well-funded, very smart, and represent a lot of votes," said Diedrich's brother Bill, 54, who sits on the region's water board.

When the Diedrich brothers moved to Firebaugh in the late 1960s, the state promised abundant water, they recalled. Back then, most crops were annual ones.

But "as water came more scarce, we had to invest in expensive material such as a dripping system, and then permanent crops to try to pay for the water," Bill Diedrich recalled.

"Now, we have this huge investment in permanent crops so we don't have the flexibility that we had back in the seventies, when you could just shut down for a year."

Jim Diedrich and his son Todd now own 535 acres (216 hectares) of almond trees and over 1,000 acres (405 hectares) of now-fallow tomato fields.

In order to keep that crop alive, the farmers have to buy water at a high price: 400 dollars per acre foot (1,200 cubic meters), for an estimated annual bill of 750,000 dollars.

"All assets we have we use to get by this year, and heaven forbid, we don't know what we're going to do next year" if water remains scarce, said Bill Diedrich.

According to a recent university study, 70,000 jobs are threatened by drought in the valley, where unemployment has already topped 20 percent in some areas.

"Now we know how the Indians felt" when colonizers stripped them of their land and their rights, Jim said. "We've got the same treatment."

Now fallow, some fields in Firebaugh have already returned to their natural state -- grassland for sheep.

"Some say that this should never have been farmland. But in that case, Los Angeles should never have been Los Angeles!" said Bob Diedrich, 57.
But "Los Angeles was a desert also," he recalled.

Antarctic Seabed Coring

The conclusions cited here appear to conflict with other available proxies that are themselves interpretive. I likely need access to the data itself so that it may be compared and perhaps correlated. The conclusions are a bit to glib and discovering the weaknesses of other data sets makes one skeptical and cautious.

I have one hundred thousand year cycles in the ice cores or perhaps they are forty thousand year cycles. It does not seem likely, does it?

I suspect that uniform cycles were observed and they convinced themselves that the proper time component was forty thousand years. I am beginning to think that trusting any age assignment is reckless.

I also observe the crustal shift conjecture would have made the western ice sheet specifically more vulnerable to a full melt and that is not necessarily true today.

We will have to keep our eyes open for the papers and the data.
I hate to be a spoil sport, but a careful reading of the material strongly suggests that they have linked the data to the known Milankovitch cycle and have corelated their data accordingly. If in fact the data is actually reflecting the 100,000 Sirius orbit then the data has been distorted by a factor of 2.5.
More importantly, the Milankovitch cycle is a very unlikely contender as a causitive agent for full polar melting. The variation is not convincing enough. However, a passage through the high infrared environment of Sirius is very convincing. Space habitats are looking better all the time when the earth turns into an alligator swamp.
Antarctic drilling yields global warming insights

http://www.chicagotribune.com/news/local/chi-antarctica-climate-change-web,0,2872493.story

By William Mullen Tribune reporter
1:46 PM CDT, March 18, 2009

Scientists studying the geophysical mechanisms behind the periodic cycles of freezing and melting at the polar ends of the earth reported today that Earth is headed toward another thaw, though it might take a thousand years or more for it to happen.

The research comes from cores drilled out of the ocean floor in Antarctica in 2006. The drilling project, co-directed by a scientist from
Northern Illinois University and known as ANDRILL, was one of the largest science projects ever undertaken on the continent.

In a report published on the cover of the research journal Nature, the researchers found that during the Pliocene epoch 3 to 5 million years ago--a time when conditions in Antarctica are similar to today's -- the ice in Antarctica collapsed and melted on a regular basis, raising world sea levels.

Polar ice began melting on a massive scale when atmospheric carbon dioxide levels were up to around 400 parts per million in the Pliocene, said Northern Illinois University geologist Ross Powell, one of the chief ANDRILL scientists. "Today and we are now at 386 parts per million and rising," he said, and it grows by one part per million every year, thanks to carbon dioxide that human activity is putting into the atmosphere.

Scientists are particularly concerned about the West Antarctic Ice Sheet, which has collapsed with great regularity about every 40,000 years and is currently in an unstable state. If all the ice atop West Antarctica today melted, it would raise world sea levels 16 feet, inundating major cities and coastal areas where billions of people live.Two climate modelers, David Pollard of
Pennsylvania State University and Robert DeConto of the University of Massachusetts, say the ANDRILL data suggest it probably would take 1,000 or more years from the beginning of a warm-up until the ice sheet would melt away.

Over the Earth's geologic history, polar freeze/thaw cycles have occurred about every 40,000 years because of a natural shift in the tilt of the Earth's axis known as the Milankovitch Cycle.

"The tilting changes the amount of radiation absorbed into each hemisphere of the Earth, depending on which hemisphere is tilted closest to the sun," said Powell. That leads to a gradual build-up of atmospheric carbon dioxide, he said, and eventually destabilizes and melts the ice shelves and ice sheets in Antarctica.
But human activity appears to be having its own effect on the world's climate, by driving temperatures warmer than they otherwise would be, said geologist Reed Scherer, also a member of the ANDRILL team from Northern Illinois University.

"If something is an external cycle," Scherer said. "It should be predictable. But it is much more complicated than that, and we seem to be throwing the pattern off balance now. It used to be that carbon dioxide rises were driven by the cycle. Now atmospheric carbon dioxide is driving the system."

In the past, everything known about climate history came from geological data collected in the northern hemisphere and very little scientific data existed from Antarctica, which holds 70 percent of the world's fresh water as ice atop the continent.

The ANDRILL core, extracted by a rig constructed atop an ice shelf in west Antarctica's Ross Sea, is the first detailed geological data on Antarctic climate history, giving scientists and climate modelers a far more complete picture of world climate history.
Earth's average annual temperature has risen 1.4 degrees Fahrenheit in the last 100 years, but over west Antarctica it has risen 4.5 degrees.

DeConto said that the historical data provided by ANDRILL has been a great milestone in climate understanding but that the role of heating and cooling ocean temperatures is even more pertinent to the stability of both the Antarctic ice sheets and the ice shelves that surround the continent.

"The next big step," said DeConto, "is to determine what is happening to the ocean temperatures under the ice shelves and around the ice sheet. We really need that information."

TR10 Liquid Battery

I am not sure that this is that exciting except to say that is long overdue that we worked with the full range of chemicals. Their trick is to allow mechanical separation to carry the separation task. This is not dissimilar to the vanadium battery and the divergence is strong enough to suggest that it will be as reliable.

Now for our next trick, let us get the energy density up.

Again, it is easy to imagine tankage doing the energy storage work with this device although it would have to be kept hot which is no problem when used with a power station.

This actually promises to be superior strategy when combined with large power output. Fit these into a grid, and it becomes simple to match demand on an as needed basis allowing optimization with all overages carried by the batteries.

And why was this problem not tackled a century ago? The method below is nineteenth century capability.


TR10: Liquid Battery

http://www.technologyreview.com/energy/22116/

Donald Sadoway conceived of a novel battery that could allow cities to run on solar power at night.

Without a good way to store electricity on a large scale, solar power is useless at night. One promising storage option is a new kind of battery made with all-liquid active materials. Prototypes suggest that these liquid batteries will cost less than a third as much as today's best batteries and could last significantly longer.

The battery is unlike any other. The electrodes are molten metals, and the electrolyte that conducts current between them is a molten salt. This results in an unusually resilient device that can quickly absorb large amounts of electricity. The electrodes can operate at electrical currents "tens of times higher than any [battery] that's ever been measured," says Donald Sadow­ay, a materials chemistry professor at MIT and one of the battery's inventors. What's more, the materials are cheap, and the design allows for simple manufacturing.

The first prototype consists of a container surrounded by insulating material. The researchers add molten raw materials: antimony on the bottom, an electrolyte such as sodium sulfide in the middle, and magnesium at the top. Since each material has a different density, they naturally remain in distinct layers, which simplifies manufacturing. The container doubles as a current collector, delivering electrons from a power supply, such as solar panels, or carrying them away to the electrical grid to supply electricity to homes and businesses.

http://www.technologyreview.com/energy/22116/page2/

Discharged, charging, charged: The molten active components (colored bands: blue, magnesium; green, electrolyte; yellow, antimony) of a new grid-scale storage battery are held in a container that delivers and collects electrical current (left). Here, the battery is ready to be charged, with positive magnesium and negative antimony ions dissolved in the electrolyte. As electric current flows into the cell (center), the magnesium ions in the electrolyte gain electrons and form magnesium metal, which joins the molten magnesium electrode. At the same time, the antimony ions give up electrons to form metal atoms at the opposite electrode. As metal forms, the electrolyte shrinks and the electrodes grow (right), an unusual property for batteries. During discharge, the process is reversed, and the metal atoms become ions again.

As power flows into the battery, magnesium and antimony metal are generated from magnesium antimonide dissolved in the electrolyte. When the cell discharges, the metals of the two electrodes dissolve to again form magnesium antimonide, which dissolves in the electrolyte, causing the electrolyte to grow larger and the electrodes to shrink (see above).

Sadoway envisions wiring together large cells to form enormous battery packs. One big enough to meet the peak electricity demand in New York City--about 13,000 megawatts--would fill nearly 60,000 square meters. Charging it would require solar farms of unprecedented size, generating not only enough electricity to meet daytime power needs but enough excess power to charge the batteries for nighttime demand. The first systems will probably store energy produced during periods of low electricity demand for use during peak demand, thus reducing the need for new power plants and transmission lines.

Many other ways of storing energy from intermittent power sources have been proposed, and some have been put to limited use. These range from stacks of lead-acid batteries to systems that pump water uphill during the day and let it flow back to spin generators at night. The liquid battery has the advantage of being cheap, long-lasting, and (unlike options such as pumping water) useful in a wide range of places. "No one had been able to get their arms around the problem of energy storage on a massive scale for the power grid," says Sadoway. "We're literally looking at a battery capable of storing the grid."

Since creating the initial prototypes, the researchers have switched the metals and salts used; it wasn't possible to dissolve magnesium antimonide in the electrolyte at high concentrations, so the first prototypes were too big to be practical. (Sadowa­y won't identify the new materials but says they work along the same principles.) The team hopes that a commercial version of the battery will be available in five years.

General Fusion MTF Power Generation

This material describes another serious attempt to produce sustainable fusion energy and it is interesting. I am somewhat skeptical that this will actually succeed, if only because I find it difficult to believe that this contraption can be made to work physically. I would not want the build out job.

The images need to be looked at individually as they are much better enlarged.

At least we are now getting a number of serious attempts at producing fusion energy, even when the protocol is not obviously promising. We need that because the breakthrough may come from a special insight on one of these rigs.

One attraction to this system is the fact that neutrons will be absorbed by the working fluid and carried off. It can not be that simple but it is still a major improvement.

Otherwise, this protocol is meant to run hot and to directly support a thermal power generation system which makes it very attractive to the power industry in general. It really is a stand alone power generator that one can envisage in a power plant.

I am also pleased to see that they are exploiting physical shock waves. I have occasionally pondered that problem over the years after I came across some work that was suggestive in that direction. A shock wave has enough energy to approach the levels we will need. Fortunately not easily enough for accidental events.

General Fusion's Approach

General Fusion is using the MTF approach but with a new, patent pending and cost-effective compression system to collapse the plasma.

General Fusion will build a ~3 meter diameter spherical tank filled with liquid metal (lead-lithium mixture). The liquid is spun to open up a vertical cylindrical cavity in the center of the sphere (vortex). This vortex flow is established and maintained by an external pumping system; the liquid flows into the sphere through tangentially directed ports at the equator and is pumped out radially through ports near the poles of the sphere. Two spheromaks (self confined magnetized plasma rings) composed of the deuterium-tritium fuel are then injected from each end of the cavity. They merge in the center to form a single magnetized plasma target. The outside of the sphere is covered with pneumatic rams. The rams use compressed gas to accelerate pistons to ~50 m/s. These pistons simultaneously impact a set of stationary anvil pistons at the surface of the sphere, which collectively launch a high pressure spherical compression wave into the liquid metal. As the wave travels and focuses towards the center, it becomes stronger and evolves into a strong shock wave. When the shock arrives in the center, it rapidly collapses the cavity with the plasma in it. At maximum compression the conditions for fusion are briefly met and a fusion burst occurs releasing its energy in fast neutrons. The neutrons are slowed down by the liquid metal causing it to heat up. A heat exchanger transfers that heat to a standard steam cycle turbo-alternator to produce electricity for the grid. Some of the steam is used to run the rams. The lithium in the liquid metal finally absorbs the neutrons and produces tritium that is extracted and used as fuel for subsequent shots. This cycle is repeated about one time per second.

The overall energy balance with this design is as follows. During each cycle ~100 MJ of kinetic energy from the pistons is converted into ~15 MJ of compressional work done on the target plasma, which based on conservative estimates of energy loss rates (Bohm) within the plasma, would raise the temperature of the plasma from 100 eV to a peak of 10 keV, and increase plasma density from 1017 cm-3 to a peak of 1020 cm-3 with a dwell time at peak compression of 7 microseconds (FWHM). The magnetic field of the plasma would also increase during compression from 10 Tesla to a peak value of 1000 Tesla. Under these conditions the plasma would yield ~600 MJ of fusion energy per pulse, which would be directly converted into thermal energy of the liquid metal distributed across the neutron penetration depth (e-folding distance ~30 cm). This 600 MJ of thermal energy can be converted via a heat exchange system into ~200 MJ of useful mechanical or electrical energy (1/3 efficiency). Thus ~100 MJ would go back into the piston kinetic energy of the next pulse, and ~100 MJ of electric energy would be put onto the grid as electricity. Outputting 100 MJ per pulse, and repeating once every second would yield an overall power output of 100 megawatts.

The use of low-tech pneumatic rams in place of intrinsically expensive high power pulsed electrical systems reduces the cost of the energy delivered to the plasma by a factor of 10 making such a power plant commercially competitive even against the cheapest fossil fuel.

Because the fusion plasma is totally enclosed in the liquid metal, the neutron flux at the reactor wall is very low. Other fusion schemes struggle with a high neutron flux at the wall that rapidly damages the machine and also produces some radioactive material. General Fusion's innovative use of the liquid metal wall provides a simultaneous solution of the multiple technical constraints needed to make fusion energy production a practical reality.

The liquid metal is used to rapidly push energy into the plasma via compressional heating, hold it at maximum pressure for long enough for the fusion output to be significant, efficiently absorb the fusion output energy, and protect the mechanical structure of the device during fusion.

The pumping system that creates the vortex flow also provides a natural means to extract the fusion-heated liquid metal and run it through a heat exchanger to drive a turbine and produce electricity. Unlike other pulsed fusion concepts, with the General Fusion design no structural elements are destroyed during the fusion pulse. This enables rapid pulse repetition rates and low cost of operation since the direct cost of each pulse is only the cost of the fuel that is burned.

General Fusion is in the process of patenting this technology and believes that a reactor working on this principle could be built at a much lower cost than using the conventional magnetic and laser fusion approaches. Such a power plant would make fusion a commercially viable clean power source.

At General Fusion we are creating a world-class research facility to develop the technological and physics base to enable a breakeven magnetized target fusion experiment at the end of four years time. The new approach being pursued by General Fusion has the potential to yield the first economically viable fusion reactor, leading to commercialization and widespread use of fusion energy on a much more rapid timeline than any other route currently being considered. General Fusion is working in alliance with academic, industrial and governmental partners to implement a well-supported research and development pathway for this alternative approach to practical fusion energy.

"The closest to a potential reactor scheme is what General Fusion is proposing." - R. Kirkpatrick, Los Alamos National Laboratory [Popular Science, Janury 2009]

General Fusion Research Update

General Fusion is using the MTF (Magnetized Target Fusion) approach but with a new, patent pending and cost-effective compression system to collapse the plasma. They describe the injectors at the top and bottom of the above image in the new research paper. The goal is to build small fusion reactors that can produce around 100 megawatts of power. The company claims plants would cost around US$50 million, allowing them to generate electricity at about four cents per kilowatt hour.
If there are no funding delays, then in 2010-2011 for completion of the tests and work for an almost full scale version (2 meters instead of 3 meter diameter).

The third phase for General Fusion is to raisee $50 million for a net energy gain device with a target date of 2013 if the second/third phase are roughly on schedule.

If they get $300-500 million for commercialization, the first commercial scale unit could be 2016-2018.

Note: Any fusion power system would have applications for space. Lowering energy costs helps with space. Better and lighter power systems are good for space colonies and industrialization.

General Fusion will build a ~3 meter diameter spherical tank filled with liquid metal (lead-lithium mixture). The liquid is spun to open up a vertical cylindrical cavity in the center of the sphere (vortex). This vortex flow is established and maintained by an external pumping system; the liquid flows into the sphere through tangentially directed ports at the equator and is pumped out radially through ports near the poles of the sphere. Two spheromaks (self confined magnetized plasma rings) composed of the deuterium-tritium fuel are then injected from each end of the cavity. They merge in the center to form a single magnetized plasma target. The outside of the sphere is covered with pneumatic rams. The rams use compressed gas to accelerate pistons to ~50 m/s. These pistons simultaneously impact a set of stationary anvil pistons at the surface of the sphere, which collectively launch a high pressure spherical compression wave into the liquid metal. As the wave travels and focuses towards the center, it becomes stronger and evolves into a strong shock wave. When the shock arrives in the center, it rapidly collapses the cavity with the plasma in it. At maximum compression the conditions for fusion are briefly met and a fusion burst occurs releasing its energy in fast neutrons. The neutrons are slowed down by the liquid metal causing it to heat up. A heat exchanger transfers that heat to a standard steam cycle turbo-alternator to produce electricity for the grid. Some of the steam is used to run the rams. The lithium in the liquid metal finally absorbs the neutrons and produces tritium that is extracted and used as fuel for subsequent shots. This cycle is repeated about one time per second.

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General Fusion report on the development of compact toroid (CT) accelerators to create the target plasma for magnetized target fusion (MTF) devices. Due to the requirements of high initial density of *10^17 cm-3, strong internal fields of 5–10 T, and base temperatures of [100 eV, a design based on conical compression electrodes is an effective avenue to pursue. Progress is being made at General Fusion Inc, (Vancouver, Canada) to develop a pair of large CT accelerators for generating an MTF target plasma. In this design, tungsten coated conical electrodes (with a formation diameter of 1.9 m, a radial compression factor of 4, and overall accelerator length of 5 m) will be used to achieve ohmic heating and acceleration of the CT, yet with low wall sputtering rates. A pair of these accelerators can be synchronized and shot at one another, producing a collision and reconnection of the two CTs within the center of an MTF chamber. Depending on the choice of relative helicities, the two CTs will merge to form either a spheromak-like or an FRC-like plasma. [FRC is field reversed configuration.

An FRC (field reversed configuration) is an elongated plasma ellipsoid conducting an azimuthal current which reverses the direction of an externally applied magnetic field. The resultant field provides for toroidal plasma confinement without requiring a toroidal vacuum vessel or coil set.
Experimental Results from the First Proof of Concept System

Thursday, March 19, 2009

Super Capacity Super Capacitor

The news keeps coming. This development promises a power delivery of one megawatt per kilo of device and an energy density up there with the super capacitors.

The fabrication method sounds like it could be easily automated. This strategy is very clear and also very convincing. I cannot comment on how it compares to EEStor as they are clearly using a different approach and it is not fully described yet. They do claim that commercial delivery is soon.

This means though that the advent of a commercial device is soon form either approach.. Such a device will swiftly convert the automobile industry to electric just as quickly as possible.

Atomic construction yields punchier power store

Devices from electric cars to laptops could benefit from a new kind of capacitor, which combines the best features of conventional devices to store a large quantity of charge and release it rapidly.

Electrostatic capacitors store charge on the surface of two conducting plates separated by an insulating layer. Their advantage is that they can store and release energy much faster than batteries.

That makes them ideal candidates to replace batteries in devices that require speedy discharge of power, such as electric cars. However, electric capacitors can hold only limited charge. Supercapacitors that store charge chemically as well as electrically have
greater capacities, but perform only as well as the best batteries.

Now a prototype capacitor has been made that manages to store power as densely as a supercapacitor, but deliver it at speeds comparable with electrostatic capacitors.

Best of both worlds

It was made by chemist
Gary Rubloff at the University of Maryland, with colleagues from the Korea Advanced Institute of Science and Technology.

The secret to the prototype's performance is that it actually has 10 billion tiny capacitors, each just 50 nanometres across, crammed into every square centimetre. Electrodes connect up the mini devices so they can function as a single unit.

The team starts the creation of such small capacitors by anodising – adding a surface layer of oxide – a sheet of aluminium foil to create a regularly spaced array of nanopores across its surface. Each pore is then filled with three nested, concentric layers of material that function as the traditional conductor-insulator-conductor arrangement of an electric capacitor.

The conducting layers are made from titanium nitride, and the insulating layer from aluminium oxide. They are laid down with a highly precise way of depositing nanoscale structures called
atomic layer deposition (see image).

Atomic precision

That technique makes it possible to create thin layers of metals with unprecedented accuracy, says Rubloff: That is why the semiconductor industry is heavily pursuing atomic layer deposition to make a next generation of computer chips, he adds.

The resulting capacitor can deliver energy at a speed typical of electrostatic capacitors, at a rate that would allow a single kilogram to deliver one megawatt of power – enough to power 10,000 100-watt light bulbs. It can also store energy as densely as a supercapacitor, with 1 kg holding 2500 joules.

"Our primary target [for this technology] is as part of a hybrid battery-capacitor system for electric cars," says Rubloff. "But there are many [potential] small scale applications, [including] better electrical storage systems for cellphones or laptops."

The next step is to tweak the design to improve its performance – for instance, the team will experiment with deeper pores that can each hold bigger capacitors and thus store more energy.

Journal reference:

Great Image:

Arsenic and Old Algae

This item will surely mean very little to folks who are not into the vagarities of the mining industry. Arsenic, unlike copper and zinc and most other metals that we use is extremely toxic. It also does not remove itself from the environment very easily. It is also toxic to most of the critters that might handle it.

It is the one impurity that you can usually count on to be present and to be an inconvenience. What is more, it loves to hang around and surprise you from time to time. It is the sucker that gets into the local water supply and gets noticed.

In other words it is like a stack of dirty clothes belonging to a long departed boarder that no one wants to or can deal with and use.

So discovering an unusual bug that just loves to take out the wash is very welcome. We now have the inkling of a biological process able to render arsenic and its compounds harmless or at least less toxic. This will be helpful at many mine sites were arsenic is often a managed hazard.

Yellowstone arsenic no match for toxic-loving alga in MSU study

March 10, 2009 -- By Evelyn Boswell, MSU News Service

http://www.montana.edu/cpa/news/nwview.php?article=6911

http://www.montana.edu/cpa/news/images/articles/img200903091236616214.jpg


Tim McDermott at Lemonade Creek in Yellowstone National Park. The hot spring fed-creek is green because the arsenic-eating algae have formed a thick mat. (Photo courtesy of Tim McDermott).


BOZEMAN -- Arsenic may be tough, but scientists have found a Yellowstone National Park alga that's tougher.

The alga -- a simple one-celled algae called Cyanidioschyzon -- thrives in extremely toxic conditions and chemically modifies arsenic that occurs naturally around hot springs, said
Tim McDermott, professor in the Department of Land Resources and Environmental Sciences at Montana State University.

Cyanidioschyzon could someday help reclaim arsenic-laden mine waste and aid in everything from space exploration to creating safer foods and herbicides, the scientists said.

The alga and how it detoxifies arsenic are described in a paper that's posted the week of March 9 in the online edition of Proceedings of the National Academy of Sciences, or PNAS. Principal investigators are McDermott, Barry Rosen of Florida International University, and X. Chris Le of the University of Alberta, Canada. Among the six co-authors is Corinne Lehr, who formerly worked with McDermott as a postdoctoral scientist at MSU and is now a faculty member at California Polytechnic State University.

"This is a nice example of productive interdisciplinary collaboration," Le said. "I am pleased that we were able to contribute our analytical expertise to the identification and detection of the volatile arsenic compounds released by the algae."

Arsenic is the most common toxic substance in the environment, ranking first on the Superfund list of hazardous substances, the researchers wrote in their paper. McDermott said arsenic is very common in the hot, acidic waters of Yellowstone and presents real challenges for microorganisms living in these conditions. Indeed, there are challenges for the researchers.
McDermott said the acid in the soil and water is strong enough that it sometimes eats holes through his jeans when he kneels to collect samples.
McDermott has worked in Yellowstone for more than a decade and travels year-round to the Norris Geyser Basin to study the microbial mats that grow in acidic springs. Over the years, he noticed thick algae mats that were so lush and green in December that they looked like Astro Turf, McDermott said. By June, they were practically gone. While investigating the change, McDermott and his collaborators learned about the Cyanidiales alga and its ability to reduce arsenic to a less dangerous form.
"These algae are such a dominant member of the microbiology community that they can't escape notice, but for some reason they have not attracted much attention," McDermott said.

The Cyanidioschyzon algae grow all over Yellowstone, but the researchers concentrated on the Norris Geyser Basin, McDermott said. The alga thrives in water up to 135 degrees Fahrenheit (too hot to shower) with a very acidic pH factor ranging from 0.5 to 3.5. Creeks are considered acidic if their pH factor is less than 7.

"These algae live in areas of Yellowstone that are extremely toxic with respect to arsenic," McDermott said. "You couldn't drink these waters even if you changed their pH."

The scientists cloned genes from the alga, then studied the enzymes to figure out how they transformed arsenic. They learned that the alga oxidizes, reduces and converts arsenic to several forms that are less toxic than the original.

Rosen said one significant form is a gas that can evaporate, especially at the high temperatures of the Yellowstone springs. That allows life to exist in "really deadly concentrations of arsenic," he said.

"It gives us insight into how life adapts to extreme environments," Rosen added. "If life can grow at high temperatures and high concentrations of heavy metals like arsenic, life might be able to evolve on other planets or moons such as Titan or Enceladus."

McDermott said the scientists conducted basic research that may have implications someday for acid mine drainage and acid rock drainage remediation efforts.

"Any time you learn anything about eukaryotic algae and their potential application for bioremediation, that's always good," he said.

Eukaryotic refers to microorganisms that have cells with membranes enclosing complex structures. Cyanidioschyzon is a simple one-celled organism classified as a red algae.

Rosen added that the alga they studied is a primitive plant, so it might shed light on how plants can tolerate arsenic, which is used in several types of herbicides. The knowledge they gained could also be used someday to help create a new type of rice.

"Some plants, such as rice, accumulate high concentrations of arsenic. This endangers our food supply," Rosen explained. "Rice with high amounts of arsenic won't kill anyone quickly, but does increase the risk of cancers such as bladder cancer."

McDermott said when he first thought about investigating the changing colors in the Yellowstone algae mats, he figured that something more than photosynthesis had to be involved. He thought altitude and latitude played a role. Some of the hot springs have no trees around them, so he wondered if the intense June sun was hammering the algae.

Molecular evidence suggests that the algae in these springs are comprised of two different population groups, McDermott said. One flourishes in the winter and the other in the summer. The algae that dominates in the summer can apparently tolerate high levels of ultraviolet rays.

McDermott's study was funded by the National Science Foundation and partially by a NASA grant through MSU's Thermal Biology Institute. Rosen's work was supported by the National Institutes of Health.

Evelyn Boswell, (406) 994-5135 or
evelynb@montana.edu