This schematic diagram of a thin film organic solar cell shows the top layer, a patterned, roughened scattering layer, in green. The organic thin film layer, shown in red, is where light is trapped and electrical current is generated. The film is sandwiched between two layers that help keep light contained within the thin film.
Ultra-thin solar cells can absorb sunlight more efficiently than the thicker, more expensive-to-make silicon cells used today, because light behaves differently at scales around a nanometer (a billionth of a meter), say Stanford engineers. They calculate that by properly configuring the thicknesses of several thin layers of films, an organic polymer thin film could absorb as much as 10 times more energy from sunlight than was thought possible.
If you go down to the nanoscales that we are interested in, hundreds of millionths of a millimeter in scale, it turns out the wave characteristic really becomes important.
Visible light has wavelengths around 400 to 700 nanometers (billionths of a meter), but even at that small scale, Fan said, many of the structures that Yu analyzed had a theoretical limit comparable to the conventional limit proven by experiment.
"One of the surprises with this work was discovering just how robust the conventional limit is," Fan said.
It was only when Yu began investigating the behavior of light inside a material of deep subwavelength-scale – substantially smaller than the wavelength of the light – that it became evident to him that light could be confined for a longer time, increasing energy absorption beyond the conventional limit at the macroscale.
"The amount of benefit of nanoscale confinement we have shown here really is surprising," said Yu. "Overcoming the conventional limit opens a new door to designing highly efficient solar cells."
Yu determined through numerical simulations that the most effective structure for capitalizing on the benefits of nanoscale confinement was a combination of several different types of layers around an organic thin film.
He sandwiched the organic thin film between two layers of material – called "cladding" layers – that acted as confining layers once the light passed through the upper one into the thin film. Atop the upper cladding layer, he placed a patterned rough-surfaced layer designed to send the incoming light off in different directions as it entered the thin film.
By varying the parameters of the different layers, he was able to achieve a 12-fold increase in the absorption of light within the thin film, compared to the macroscale limit.
Nanoscale solar cells offer savings in material costs, as the organic polymer thin films and other materials used are less expensive than silicon and, being nanoscale, the quantities required for the cells are much smaller.
The organic materials also have the advantage of being manufactured in chemical reactions in solution, rather than needing high-temperature or vacuum processing, as is required for silicon manufacture.