This vase is a delightful demonstration of possibilities and is certainly driving research. All good. It is also neat work by ancient goldsmiths that clearly was treasured. We need to replicate that .
I suspect that using similar methods as i describe below we can use a range of metals to discover a range of effects.
Cobalt and cadmium come immediately to mind. Been embedded in the glass, a simple wash with a gently acid would clean the surface to a fine level of safety.
Ancient Roman Nanotechnology Inspires Next-Generation Holograms for Information Storage
By April Holloway | October 19, 2014
http://www.theepochtimes.com/n3/1028446-ancient-roman-nanotechnology-inspires-next-generation-holograms-for-information-storage/
The Lycurgus Cup,
as it is known due to its depiction of a scene involving King Lycurgus
of Thrace, is a 1,600-year-old jade green Roman chalice that changes
colour depending on the direction of the light upon it. It baffled
scientists ever since the glass chalice was acquired by the British
Museum in the 1950s, as they could not work out why the cup appeared
jade green when lit from the front but blood red when lit from behind.
Later research confirmed the effect was caused by interference
produced by the interaction of light with metallic nanoparticles. Now
the same technology used to produce the unique features of the Lycurgus
cup are being used to create holograms made of tiny particles of silver
that could double the amount of information that can be stored in
digital optical devices, such as sensors, displays and medical imaging
devices.
According to a new study published in the Proceedings of the National Academy of Sciences of the United States of America,
the interference produced by the interaction of light with
nanoparticles allows holograms to go beyond the normal limits of
diffraction, or the way in which waves spread or bend when they
encounter an opening or obstacle.
When metallic particles have dimensions on the nanoscale, they
display iridescent colours. The first known example of this phenomenon
is the Lycurgus cup, a 4th century chalice made of glass impregnated
with particles of silver and gold, ground down until they were as small
as 50 nanometres in diameter, less than one-thousandth the size of a
grain of table salt. This produced the optical phenomenon, known as
dichroism, which occurs when the colour of the cup changes from green to
red according to the position of the light source.
Scientists say the Roman artisans created the dichromic effect in the
magnificent Lycurgus chalice by accident, however, others have argued
that their work was so precise that it is ridiculous to assert that the
outcome was accidental. In fact, the exact mixture of the previous
metals suggests that the Romans had perfected the use of nanoparticles –
“an amazing feat,” according to archaeologist Ian Freestone of
University College London.
[ an accident is simply not possible. The way to do it though would be to mix fine gold and fine silver with ample fine silica glass and tumble it all for a long time until the gold and silver failed to separate out. This would provide the charge for making the vase. - arclein ]
Only in the last 20 years have scientists begun to understand the
phenomenon observed in the Lycurgus Cup, but until now, they have not
been able to utilise its effects in currently-available technology.
To apply this phenomenon in modern optics, an interdisciplinary team
of researchers have created nanoscale metallic nanoparticle arrays that
mimic the colour effects of the Lycurgus cup, to form multi-colour
holograms. This breakthrough could lead to the shrinkage of standard
bulky optical devices.
“This technology will lead to a new range of applications in the area
of photonics, as conventional optical components simply cannot achieve
this kind of functionality,” said Yunuen Montelongo, a PhD student from
the Department of Engineering, who led the research. “The potential of
this technology will be realised when they are mass produced and
integrated into the next generation of ultra-thin consumer
electronics.”
Using a single thin layer of silver, Montelongo and his colleagues
patterned colourful holograms containing 16 million nanoparticles per
square millimetre. Each nanoparticle, approximately 1000 times smaller
than the width of a human hair, scatters light into different colours
depending on its particular size and shape. The scattered light from
each of the nanoparticles interacts and combines with all of the others
to produce an image.
The device can display different images when illuminated with a
different colour light, a property not seen before in a device of this
type. Furthermore, when multiple light sources are shone simultaneously,
a multi-colour image is projected.
“This hologram may find a wide range of applications in the area of
displays, optical data storage, and sensors,” said PhD student Calum
Williams, a co-author of the paper. “However, scalable approaches are
needed to fulfil the potential of this technology.”
Isn’t it ironic that scientists now turn to the works of our
so-called ‘primitive’ ancestors for help in developing new technologies?
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