Fuel Cell and Waste Water

One wonders whether this is going anywhere, however it is intriguing enough. It would be nice if this could be combined with methane production to fully reduce a charge of organic waste to a mineralized sludge that could then be dried and blended with biochar and some soil to commence the integration. One often forgets to do that last step, yet is allows greater ease of handling. Black sludge is otherwise rather unpromising on those terms.

The problem is that it all ends up with vat based processing. A pond is always cheaper and easier however inefficient. Someone has to swallow hard and make it all happen and not quit until it is reasonably perfected.

I think though that it can be done and should be mastered in all its available variations because it just happens to impact everyone on Earth every day.

Fuel Cell Treats Waste water and Harvests Energy

A microbe-based technology does it all. Bye-bye, sewage. Hello, power

By Katherine Tweed  | July 16, 2012

http://www.scientificamerican.com/article.cfm?id=microbial-fuel-cell-treats-wastewater-harvests-energy

A new microbial fuel cell creates energy during wastewater treatment and also vastly reduces the amount of sludge produced. Israel-based company, Emefcy, named as a play on the acronym for microbial fuel cell (MFC), starts with the same principle as most wastewater treatment—water is aerated so bacteria in the liquid break down organic material in a closed series of containers known as a bioreactor.

"We didn't invent anything scientifically new," says Ely Cohen, vice president of marketing and business development for the four-year-old company.

The novelty factor: instead of using electricity to push air into the water, Emefcy uses a permeable filter that allows air in but doesn't let liquid out, much like how a diaper works. The polyethylene plastic membrane, similar to materials used in construction, surrounds the fuel cell chamber into which wastewater flows.

Inside the fuel cell, Emefcy coaxes anaerobic bacteria, primarily Shewanella oneidensis and Geobacter sulfurreducens, to release electrons in an oxygen-free environment. The electrons flow to an anode and then into a circuit to cathodes in a separate chamber on the outside of the membrane. The electrons allow the carbon cathodes to react with oxygen to form carbon dioxide.

The practical side of the Emefcy fuel cell relates to the materials engineering: both the anode and cathode are made of a carbon cloth that acts as a conductor. Precious metals have long been used as conducting materials in batteries and other types of fuel cells but are too expensive to use at a commercial scale in microbial fuel cells.

For a typical paper-recycling factory, one Emefcy fuel cell module, which is about the size of a cubic meter, could treat about three cubic meters per day of wastewater depending on the amount of organic material present, according to Cohen, and the modules can be scaled to meet the needs of larger or smaller plants.

The bacteria eat a lot to produce electricity and live a longer life because the environment is optimized for their survival, so sludge can be cut down by 80 percent, Cohen says. Roughly four watts of electricity are produced for every kilogram of organic material that the bacteria consume. The amount of electricity generated will not exactly power the entire town, or even the entire processing facility, but it can offset the energy used to clean the water.

"The energy we don't consume is more important than the electricity we might produce," says environmental engineer Bruce Logan of Pennsylvania State University, an Emefcy advisor.

Municipal and industrial wastewater plants comprise about 2 percent of the annual electrical power used in the U.S., but treatment methods have remained largely unchanged for decades. In traditional systems, most of the power goes into pumping air through the water so that bacteria in the water can grow and consume organic material that remains after the largest particles have been removed. Another substantial chunk of energy goes into trucking away the leftover sludge, which almost always ends up in landfills.

Emefcy's technology has its limitations. The fuel cell is ideal for wastewater that is high in organic material, mostly wastewater from agriculture and food processing rather than municipalities. Logan estimates that quantities of food and beverage wastewater equal domestic wastewater, and animal and farm wastewater is more than the other two markets combined. Cohen said that the food additives industry, in particular, may become a very attractive market for the technology.

Sludge reduction and regulatory compliance are also significant drivers for the food and beverage industry, which is pushing more companies to process wastewater on site rather than just sending it directly to municipal treatment facilities, according to a report from Global Water Intelligence (GWI), a water industry market research firm based in England. With increasing regulation, Emefcy's technology could become appealing for this market as well.

Emefcy is building a demonstration plant in Israel that will scale up to 16 modules starting next year, and, in the lab, the company is already testing wastewater from factories across the globe. Emefcy hopes the scalable system will be available commercially some time in 2013, with a price tag of $4,000 to $5,000 per module.

Although Emefcy has garnered a lot of attention for its progress, the microbial fuel cell industry as a whole is still trying to prove whether this will really work, says Zhen He, a microbial fuel cell researcher at University of Wisconsin–Milwaukee's Environmental Biotechnology and Bioenergy Lab. He notes that of the nearly 4,000 papers published on microbial fuel cells, less than 2 percent report on processing volumes of water larger than one liter. "I don't think one group can deal with everything." he says. "We need the whole field to move this to a larger scale." But Emefcy is not alone. There are some other groups, including a team at the J. Craig Venter Institute, that are scaling pilots of a microbial fuel cell for wastewater treatment.

While Emefcy tries to cut down on sludge, other researchers look for ways to turn sludge into biofuels, such as BlackGold Biofuels in Philadelphia. Another start-up, Ostara Nutrient Recovery Technologies in Vancouver, is harvesting minerals that would usually end up in sludge and turning them into high-grade fertilizer. Anaerobic digestion is also a growing trend in the industrial wastewater industry, according to the GWI report. Other companies, like FuelCell Energy in Danbury, Conn., are capturing the gas from anaerobic digesters to be used in combined heat and powerplants.

About 104 municipal treatment plants use anaerobic digestion gas capture for a combined heat and cycle plant, according to the U.S. Environmental Protection Agency. Municipalities are also taking advantage of the falling price of solar power to offset the energy needs of wastewater plants.

Other companies are looking to harness the flow of wastewater facilities to capture at least some of the hydropower as electricity. Hydrogen is another attractive by-product of wastewater, and some of Logan's research at Penn State involves looking into how to capture hydrogen to run fuel cells.

"I think there's still some uncertainty with whether the benefit is to make electrical power or to have a hydrogen production facility," Logan says. "Right now, it's a toss-up."

Depending on the location and type of wastewater, there will likely be a market opportunity for many different solutions. "We're changing the economics of wastewater," Cohen says. "It's a tremendous source of energy."